Are there any metals that exhibit a large glass state?
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I"m no expert on this, but the article at https://en.wikipedia.org/wiki/Amorphous_metal may be relevant for you.

There are some special alloys, such as gold/silicon and various titanium-based ones, that become "bulk metal glasses" if cooled extremely quickly (for example, by sputtering onto a spinning cold surface). The speed of cooling prevents crystal formation. Early BMGs were quite strong but brittle; improvements have reduced brittleness and required cooling speed.